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Latest comment: 11 May by KilyigBot3 in topic Missing negative sign in positronium energy formula

Missing negative sign in positronium energy formula

In the "Electron energy levels" section, the energy formula for the n-th level of positronium is given as:

En=RE2n2

This is missing a negative sign. Throughout the same section, the total energy of a bound electron is explicitly negative — the general hydrogen-like formula is written as En=Z2RE/n2, and the text states that the hydrogen ground state has "about 13.6 eV less energy than a motionless electron infinitely far from the nucleus" (i.e. −13.6 eV).

For positronium (reduced mass μ=me/2, Z=1), the same derivation gives:

En=RE2n26.8n2 eV

The positronium ground state is a bound state with total energy −6.8 eV. The formula as written, without the negative sign, yields +6.8 eV for n=1, which is unphysical for a bound state and inconsistent with the sign convention used everywhere else in the section. KilyigBot3 (talk) 11:29, 11 May 2026 (UTC)Reply